High energy-density electrochemical flow capacitor

Overview

Traditional flow batteries suffer from slow response rates due to faradaic reactions at the electrode-electrolyte surface and have limited cycle lifetimes (<12,000 cycles) which is a critical factor for grid scale energy storage. In contrast, the electrochemical flow capacitor is a rechargeable electrochemical energy storage system that utilizes flow battery architecture and is based on the fundamental working principles of supercapacitors. The primary difference between traditional flow cells and the EFC is that the EFC utilizes a flowable carbon-electrolyte ‘slurry electrode’ for capacitive energy storage (see Figure below).  During operation the slurry is pumped from a storage reservoir through two polarized plates (charging process). Once fully charged, the slurry is pumped out of the cell and stored in external reservoirs until the process is reversed and the slurry is discharged. The charged slurry stores charge electrostatically at the carbon/electrolyte interface, which allows for rapid charging and discharging leading to a higher power density. Faradaic charging processes have losses that cause degradation of the device over time compared to electrostatic charging, which has near 100% efficiency and millions of charge-discharge cycles.

Applications

  • Grid scale energy storage
  • Desalination
  • Rapid energy recovery and delivery

Advantages

  • Higher power than flow batteries
  • Rapid charging and discharging
  • Long lifetime - millions of cycles
  • Safe, low-cost, non-toxic materials
  • Scalable energy storage capacity

Intellectual Property and Development Status

United States Issued Patent- 9,171,679

References

Hatzell, K. B., Beidaghi, M., Campos, J. W., Dennison, C. R., Kumbur, E. C., and Gogotsi, Y., 2013, “A high performance pseudocapacitive suspension electrode for the electrochemical flow capacitor,” Electrochimica Acta, vol. 111, pp. 888-897.

Presser, Volker, Christopher R. Dennison, Jonathan Campos, Kevin W. Knehr, Emin C. Kumbur, and Yury Gogotsi. "The electrochemical flow capacitor: a new concept for rapid energy storage and recovery." Advanced Energy Materials 2, no. 7 (2012): 895-902.

Campos, Jonathan W., Majid Beidaghi, Kelsey B. Hatzell, Christopher R. Dennison, Benjamin Musci, Volker Presser, Emin C. Kumbur, and Yury Gogotsi. "Investigation of carbon materials for use as a flowable electrode in electrochemical flow capacitors." Electrochimica Acta 98 (2013): 123-130.

 

Operational schematic of the electrochemical flow capacitor. Uncharged slurry flows through polarized plates and charged. At the pore level, electrode neutrality is maintained at the interface between the electrolyte and active material. This slurry is then pumped into external reservoirs for storage. The process is reversed during discharge.

Commercialization Opportunities

 

Contact Information

Web Site

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For Technical Information:

 

E. Caglan Kumbur, Ph.D.

Assistant Professor of Mechanical Engineering

Electrochemical Energy Systems Laboratory

Drexel University, Philadelphia, PA 19104

Ph :  215.895.5871

Fax: 215.895.1478

E-mail: eck32@drexel.edu

 

 

For Intellectual Property and Licensing Information:

Elizabeth Poppert, Ph.D.

Licensing Manager

Office of Technology Commercialization

3180 Chestnut Street, Suite 104

Philadelphia, PA 19104

Phone: 215-895-0999

Email: lizpoppert@drexel.edu

For Information, Contact:

Inventors:

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