A novel photovoltaic device including a polymer dispersed liquid crystal (PDLC) material that is capable of converting solar energy to electrical energy and method for making. The device may optionally include a conductive container for holding the PDLC material. In an exemplary embodiment, the invention is directed to a self assembled PDLC material, a holographically synthesized PDLC material or a block co-polymer dispersed liquid crystal material. It is envisioned that the invention may be used a power source for any device, system or application. In particular, the invention may be used for any application involving the conversion of solar energy to electrical energy.