MXenes
Overview
Researchers at Drexel University have created a new class of two-dimensional (2D) early transition metal carbide and carbonitride compounds known as MXenes. 2D solids, among them most notably graphene, have generated recent interest because of their outstanding properties which can be exploited for innumerable industrial and biomedical applications. Multilayer MXenes are conductively similar to multilayer graphene. However, unlike graphene, MXenes can be easily dispersed in aqueous solutions because of their hydrophilic properties. MXenes are generated from a large class (>60) of parent compounds known as MAX phases. The electrochemical optical, electronic and mechanical properties of MXenes can be optimized by selection of parent compound, surface chemistry, and intercalating cations and/or organic compounds to produce a wide array of novel materials with applications that range from electronic devices, sensors, reinforcement for composites, energy storage materials and conductive transparent electrodes.
Applications
- Energy storage, e.g. Li-ion batteries and Li-ion capacitors
- Electrochemical supercapacitors
- Electrocatalysts and photocatalysts
- Conductors and semi-conductors
- Conductive transparent electrodes
Advantages
- Electronically conducting AND hydrophilic 2D nanomaterials
- Versatile class of compounds which can be optimized for specific application by selection of parent compound, surface chemistry, and intercalating compounds
- Manufacturing process is simple, readily scalable, with high yields
Intellectual Property and Development Status
United States Issued Patent- 9,193,595
United States Issued Patent- 9,415,570
United States Issued Patent- 9,416,011
References
M. Naguib, V.N. Mochalin, M.W. Barsoum, Y. Gogotsi, 25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials, Advanced Materials, 26, 992-1005 (2014)
M. Naguib, J. Halim, J. Lu, K. Cook, L. Hultman, Y. Gogotsi, M. W. Barsoum, New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-ion Batteries, J. Am. Chem. Society, 135 (43) 15966–15969 (2013)
Commercialization Opportunities