A vortex reactor is provided. The vortex reactor includes a substantially cylindrical shaped portion forming a reaction chamber therein, wherein said substantially cylindrical shaped portion forms a first charged electrode; a circumferential flow apparatus fluidly connected to the reaction chamber for creating a circumferential fluid flow; a second charged electrode; and an outlet for releasing said circumferential fluid flow. Also provided are methods of processing particulate solids using the vortex reactor of the invention.